Extracurricular laboratory:new discovery of (4S,5R)-4-Methyl-5-phenyloxazolidin-2-one

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C10H11NO2, you can also check out more blogs about16251-45-9

Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Computed Properties of C10H11NO2. Introducing a new discovery about 16251-45-9, Name is (4S,5R)-4-Methyl-5-phenyloxazolidin-2-one

Direct Metal-Free Entry to Aminocyclobutenes or Aminocyclobutenols from Ynamides: Synthetic Applications

The [2+2] cycloaddition of ynamides with the highly polarized reagent Tf2C=CH2has been developed to regioselectively afford bis(triflyl)aminocyclobutenes in the absence of catalyst under mild conditions. Incidentally, with the ynamides bearing electron-rich aromatic rings at the C-terminal, an interesting reactivity switch was observed; a cyclization/hydroxylation sequence yielded 2-amino-3-(triflyl)cyclobut-2-enols. Aminocyclobutene construction with addition of alcohols resulted in the formation of aminocyclobutenyl ethers through a cyclization/hydroalkoxylation process. Moreover, the utility of functionalized aminocyclobutenes as precursors for further elaboration was demonstrated with the preparation of alpha-amino-beta,gamma-unsaturated ketones and 3-(triflyl)buta-1,3-dien-2-amines through 4 pi-electrocyclic ring opening.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C10H11NO2, you can also check out more blogs about16251-45-9

Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2138NO – PubChem