Electric Literature of 102029-44-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.102029-44-7, Name is (R)-4-Benzyl-2-oxazolidinone, molecular formula is C10H11NO2. In a Article£¬once mentioned of 102029-44-7
Asymmetric biomimetic oxidations of phenols using oxazolidines as chiral auxiliaries: The enantioselective synthesis of (+)- and (-)-dehydrodiconiferyl alcohol
Stereoselective bimolecular radical coupling reactions of phenylpropenoid phenols are described. Evans’s 2-oxazolidinone 11a-d derivatives of ferulic acid were prepared and oxidized to give dimeric benzofuran neolignan structures 12-13a-d in 40-50% overall yields. The chiral phenols were dimerized either enzymatically with hydrogen peroxide and horseradish peroxidase (HRP) or with silver oxide. The enantioselectivity after reductive cleavage of the chiral auxiliaries to give dehydrodiconiferyl alcohol ranged from 18% to 62% enantiomeric excess. The conformational analysis and the activation energy using semiempirical PM3 calculations on the intermediate quinomethides is used to explain the observed stereoselectivity. Copyright
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 102029-44-7, and how the biochemistry of the body works.Electric Literature of 102029-44-7
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H1748NO – PubChem