Electric Literature of 173604-33-6, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 173604-33-6, (R)-4-Benzhydryloxazolidin-2-one, introducing its new discovery.
A highly regio- and stereoselective synthesis of I±-fluorinated imides via fluorination of chiral enamides
A highly I¿-facial selective and regioselective fluorination of chiral enamides is described. The reaction involves an enantioselective fluorination exclusively at the electron-rich enamide olefin with N-F reagents such as Selectfluor and N-fluoro-benzenesulfonimide [NFSI] accompanied by trapping of the I²-fluoro-iminium cationic intermediate with water. The resulting N,O-hemiacetal could be oxidized using Dess-Martin periodinane, leading to an asymmetric sequence for syntheses of chiral I±-fluoro-imides and optically enriched I±-fluoro-ketones.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 173604-33-6. In my other articles, you can also check out more blogs about 173604-33-6
Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H2464NO – PubChem