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Gold(l)-Catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles

“Chemical Equation Presented” A 1:1 mixture of [P(t-Bu) 2-obiphenyl]AuCl and AgSbF6 catalyzes the intermolecular amination of allylic alcohols with 1-methylimldazolidin-2one and related nucleophiles that, In the case of gamma-unsubstituted or gamma-methyl- substituted allylic alcohols, occurs with high gamma-regioselectivity and syn-stereoselectivlty.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H847NO – PubChem

 

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Application of 497-25-6, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 497-25-6, molcular formula is C3H5NO2, introducing its new discovery.

Method for producing cyclic carbamate ester

A method for producing a cyclic carbamate ester produces the cyclic carbamate ester by reacting an organic compound having at least two halogen atoms per molecule, an amine having at least two hydrogen atoms on a nitrogen atom, and carbon dioxide.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H142NO – PubChem

 

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Related Products of 497-25-6, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.497-25-6, Name is Oxazolidin-2-one, molecular formula is C3H5NO2. In a article£¬once mentioned of 497-25-6

Highly mesoporous and high surface area carbon: A high capacitance electrode material for EDLCs with various electrolytes

Activated carbon fibers (ACFs) with high surface area and highly mesoporous structure for electrochemical double layer capacitors (EDLCs) have been prepared from polyacrylonitrile fibers by NaOH activation. Their unique microstructural features enable the ACFs to present outstanding high specific capacitance in aqueous, non-aqueous and novel ionic liquid electrolytes, i.e. 371 F g-1 in 6 mol L-1 KOH, 213 F g-1 in 1 mol L-1 LiClO4/PC and 188 F g-1 in ionic liquid composed of lithium bis(trifluoromethane sulfonyl)imide (LiN(SO2CF3)2, LiTFSI) and 2-oxazolidinone (C3H5NO2, OZO), suggesting that the ACF is a promising electrode material for high performance EDLCs.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1146NO – PubChem

 

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Comparative life cycle assessment of potassium carbonate and monoethanolamine solvents for CO2 capture from post combustion flue gases

Carbon capture and storage (CCS) has the potential to enable significant reductions in carbon dioxide (CO2) emissions from stationary sources such as coal-fired power stations. The most advanced carbon capture technology is CO2 absorption using amine-based solvents, such as monoethanolamine (MEA). However, there is concern that the increased use of amine-based solvents will lead to other potential negative environmental impacts, such as increased human toxicity. The use of benign inorganic solvents, such as potassium carbonate, which do not degrade in the presence of oxygen or other impurities such as sulphurous or nitrous oxides offer significant advantages over amine-based solvents in terms of environmental impact. A comparative life cycle assessment (LCA) between the use of MEA and the CO2CRC’s potassium carbonate based UNO MK 3 technology for the capture of 1tonne of CO2 from a brown-coal fired power station has been completed. The results reveal that the UNO MK 3 process is significantly better than MEA on ecotoxicity and carcinogen emissions and substantially better on all other indicators. The benefits of the UNO MK 3 process compared with MEA are due to avoidance of emissions from MEA degradation along with the savings in energy use for CO2 removal. The significant environmental benefits of the UNO MK 3 process compared with MEA were not altered by an uncertainty analysis or sensitivity analysis of key inputs and assumptions.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H569NO – PubChem

 

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Immobilization of phosphorescent quantum dots in a sol-gel matrix for acetone sensing

Quantum dots (QDs) are semiconductor nanoparticles (NPs) that are increasingly used in optical sensing applications due to their exceptional optoelectronic properties. When such nanocrystals are doped with certain metal impurities, a phosphorescence-like emission can be obtained, allowing the development of novel robust and highly selective sensing phases (it is possible to perform time resolved measurements enabling a simple discrimination between the luminescence emission from the QDs from the background fluorescence of the sample, in which luminescent lifetime is shorter). In this context, a phosphorescent sensing material for acetone control in water media has been developed based on the immobilization of phosphorescent quantum dots in an inorganic sol-gel solid matrix. For such purpose, colloidal manganese-doped ZnS nanoparticles (Mn:ZnS QDs) surface-modified with l-cysteine (for water solubilisation) were synthesised. The Mn:ZnS QDs exhibit an intense room temperature phosphorescence (RTP) emission in aqueous media even in the presence of dissolved oxygen. Further, a simple and general procedure is proposed to incorporate the colloidal l-cysteine Mn:ZnS QDs in a sol-gel matrix. Application of the developed sensing material to analytical control of acetone dissolved in contaminated water samples was performed based on measurement of the quenching effect of the analyte on the QDs phosphorescence emission. The sol-gel procedure (e.g. nature and concentration of the silica precursors used) employed for immobilization of the QDs was optimized trying to obtain the best analytical features for detection of acetone. The optimized sensing material showed a high selectivity of the sensing material towards acetone. The linear range of the developed methodology turned out to be at least up to 50% acetone:water (v/v) with a detection limit (DL) for acetone dissolved in aqueous medium of 0.16% acetone:water (v/v). The developed sensing phase was finally applied for acetone determination in different spiked water samples, and the recoveries fall in the range of 93-109%.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1017NO – PubChem

 

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Insecticidal activity of novel thioureas and isothioureas

BACKGROUND: We hypothesized that the exploration of chemical space around compounds with reported insecticidal activity could be a viable strategy for discovering novel, insecticidally active areas of chemistry. RESULTS: A series of thioureas and isothioureas were prepared as part of a scaffold-hopping effort around known insecticidal compounds. Many of these compounds showed excellent activity against key sap-feeding insect pests in insecticidal bioassays. While analogs bearing monocyclic thiophene head groups showed activity against Myzus persicae (green peach aphid), analogs with diarylethane head groups were active against both M. persicae and Bemisia tabaci (sweetpotato whitefly). Despite compelling activity in these laboratory tests, these compounds showed diminished activity when applied to host plants via tracksprayer. CONCLUSIONS: The initial hypothesis that structural modification of molecules reported to have insecticidal activity would yield novel compounds that also exhibit insecticidal activity was validated. Despite excellent activity in laboratory bioassays, these new compounds failed to show compelling activity in more demanding tracksprayer tests.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H718NO – PubChem

 

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Mechanisms, polymerization rate scaling, and oxygen inhibition with an ultra-rapid monovinyl urethane acrylate

Certain monovinyl (meth)acrylate monomers with secondary functionalities such as urethanes have been shown to exhibit extremely rapid curing rates. In this work, the polymerization mechanism, polymerization rate scaling, and relative oxygen inhibition are evaluated for an ultra-rapid butyl urethane acrylate and an analogous aliphatic urethane diacrylate. The aliphatic urethane diacrylate was found to have increased polymerization rates at higher initiation rates relative to the butyl urethane acrylate, primarily due to different termination mechanisms. Additionally, due to higher viscosity and crosslinking density, the aliphatic urethane diacrylate was found to exhibit a greater resistance to oxygen inhibition. The flux of oxygen into the aliphatic urethane diacrylate was 1/3 that of butyl urethane acrylate. Suppressed termination likely contributes to the rapid polymerization kinetics of butyl urethane acrylate.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H455NO – PubChem

 

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Enantioselective conjugate radical addition reactions mediated by chiral Lewis acid complexes of (R,R)-4,6-dibenzofurandiyl-2,2′-bis(4- phenyloxazoline) (DBFOX/Ph)

A high-yielding synthesis (50% overall yield) of tridentate bisoxazoline ligand (R,R)-4,6-dibenzofurandiyl-2,2′-bis(4-phenyloxazoline) (DBFOX/Ph) was developed. DBFOX/Ph was subsequently tested in enantioselective conjugate radical additions onto 3-(3-phenyl-2-propenoyl)-2-oxazolidinone. Two dozen Lewis acids were evaluated, and Mg(ClO4)2 emerged as the best Lewis acid in terms of yield and enantioselectivity (100% yield, 75.4% ee (S)).

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Oxazolidine – Wikipedia,
Oxazolidine | C3H638NO – PubChem

 

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Erythromycin derivatives with antibiotic activity

Erythromycin derivatives with antibiotic activity and pharmaceutically acceptable salts thereof. A process for preparing such erythromycin derivatives and pharmaceutical compositions containing them as the active principle.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H95NO – PubChem

 

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We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 497-25-6, and how the biochemistry of the body works.Formula: C3H5NO2

In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 497-25-6, name is Oxazolidin-2-one, introducing its new discovery. Formula: C3H5NO2

Cu-catalyzed amidation of halogenated imidazoles

An efficient methodology involving the Cu-catalyzed amidation of halogenated imidazoles has been successfully developed. The amidated product of 5-bromo-1-alkylimidazole was further applied to the synthesis of a new chiral imidazole nucleophilic catalyst for the kinetic resolution of secondary alcohols. The Royal Society of Chemistry 2014.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1113NO – PubChem