Heterocyclic Building Blocks-Oxazolidine

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INHIBITORS OF THE FIBROBLAST GROWTH FACTOR RECEPTOR

Described herein are inhibitors of FGFR-4, pharmaceutical compositions including such compounds, and methods of using such compounds and compositions.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1558NO – PubChem

 

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Intermolecular asymmetric reductive aldol reaction of ketones as acceptors promoted by chiral Rh(Phebox) catalyst

The conjugate reduction of cinnamates with hydrosilane and chiral Rh(Phebox-ip) catalyst in the presence of excess acetone is shown to provide the corresponding intermolecular reductive aldol product in extremely high enantioselectivity (up to 98%). Several cinnamates and crotonate substrates and several ketone acceptors were also examined.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2017NO – PubChem

 

Related Products of 95715-86-9, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.95715-86-9, Name is Methyl (R)-N-Boc-2,2-dimethyloxazolidine-4-carboxylate, molecular formula is C12H21NO5. In a article£¬once mentioned of 95715-86-9

beta-isocupreidine-catalyzed Baylis-Hillman reaction of chiral N-Boc-alpha-amino aldehydes

beta-Isocupreidine (beta-ICD)-catalyzed Baylis-Hillman reaction of chiral N-Boc-alpha-amino aldehydes and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) takes place without racemization and exhibits the match-mismatch relationship between the substrate and the catalyst. In the case of acyclic amino aldehydes, alpha,-substrates show excellent syn selectivity and high reactivity in contrast to L-substrates. On the other hand, in the case of cyclic amino aldehydes, D-substrates rather than L-substrates show excellent anti selectivity and high reactivity.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2543NO – PubChem

 

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Total synthesis of the highly N-methylated peptides carmabin a and dragomabin

The first total synthesis of carmabin A and dragomabin was achieved at 52.3 mg and 43.8 mg scale, respectively. The synthesis led to determination of the configuration of carmabin A and reassignment of the configuration of dragomabin at the stereogenic centre on the alkyne-bearing fragment.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2098NO – PubChem

 

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Synthesis of cyanoacetyl oxazolidinones

Carefully controlled displacement of chiral chloroacetyl imides with cyanide afforded previously unreported cyanoacetimides in good overall yield. Knoevenagel condensation of the cyanoacetimides to furnish acrylonitriles was also demonstrated. Georg Thieme Verlag Stuttgart . New York.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2072NO – PubChem

 

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The lyconadins: Enantioselective total syntheses of (+)-lyconadin A and (-)-lyconadin B

A full account of the enantioselective total syntheses of (+)-lyconadin A (1) and (-)-lyconadin B (2) is presented. Central to this venture was recognition and deployment of a key strategy-level intramolecular aldol/conjugate addition cascade that led, in a single operation, to two new carbon-carbon sigma-bonds, three new stereogenic centers, and two new rings, albeit with the incorrect stereogenicity at C(12) for the lyconadins. Correction of the C(12) stereogenicity was achieved via innovative use of a protonated intramolecular aminal. An aminoiodo olefin cyclization, in conjunction with alpha-pyridinone and 3,4-dihydropyridinone annulation protocols, permitted completion of the syntheses of (+)-lyconadin A (1) and (-)-lyconadin B (2), respectively.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1733NO – PubChem

 

Reference of 169048-83-3, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.169048-83-3, Name is (S)-5-(Chloromethyl)oxazolidin-2-one, molecular formula is C4H6ClNO2. In a article£¬once mentioned of 169048-83-3

Electrogenerated chiral 4-methoxy-2-oxazolidinones as diastereoselective amidoalkylation reagents for the synthesis of beta-amino alcohol precursors

A flexible and efficient synthesis of enantiomerically pure 4,5-substituted 2-oxazolidinones – important target molecules as precursors of pharmacologically active 2-oxazolidinones, beta-amino alcohols, beta-blockers and azasugar derivatives – is described. As starting materials, the enantiopure storage forms of chiral N-acyliminium ions (4RS,5S)-5-chloromethyl-4-methoxy-1,3-oxazolidin-2-one (2) and (4RS,5R)-4-methoxy-5-methyl-1,3-oxazolidin-2-one (3) were used; these are readily available from the chiral pool with the aid of electrochemical transformations. Substitution of the 4-methoxy group in building blocks 2 and 3 with a large variety of organometallic nucleophiles resulted in the trans-diastereoselective formation of enantiopure 4,5-disubstituted 2-oxazolidinones, with a high degree of flexibility in the substituent at the 4-position.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1401NO – PubChem

 

497-25-6, Name is Oxazolidin-2-one, belongs to oxazolidine compound, is a common compound. Recommanded Product: Oxazolidin-2-oneIn an article, once mentioned the new application about 497-25-6.

Microwave-assisted preparation of cyclic ureas from diamines in the presence of ZnO

A MW-assisted direct synthesis of cyclic ureas has been developed that proceeds expeditiously in the presence of ZnO thus shortening its reaction time; the process also eliminates the formation of byproducts when compared to the traditional methods involving conventional heating. A microwave-assisted facile method for the preparation of various ureas, cyclic ureas, and urethanes has been developed that affords nearly quantitative yield of products at 120C (150 W), 71 kPa within 10 min using ZnO as a catalyst. The enhanced selectivity in this reaction is attributed to the deployment of ZnO whose absence results in poor yield and the generation of byproducts.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H692NO – PubChem

 

Reference of 102029-44-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.102029-44-7, Name is (R)-4-Benzyl-2-oxazolidinone, molecular formula is C10H11NO2. In a Article£¬once mentioned of 102029-44-7

Design and synthesis of 3-arylpyrrolidine-2-carboxamide derivatives as melanocortin-4 receptor ligands

Based on 3-phenylpropionamides, a series of 3-arylpyrrolidine-2-carboxamide derivatives was designed and synthesized to study the effect of cyclizations as melanocortin-4 receptor ligands. It was found that the 2R,3R-pyrrolidine isomer possessed the most potent affinity among the four stereoisomers.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2054NO – PubChem

 

Application of 695-53-4, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 695-53-4, molcular formula is C5H7NO3, introducing its new discovery.

Dye-forming coupler, silver halide photographic light-sensitive material, and azomethine dye compound

A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye compound derived from the coupler: wherein Q is a residue that forms, together with the -N-CN- moiety, a nitrogen-containing 6-membered ring; RA is a certain alkyl group having at least 7 carbon atoms, or -L-R1; X is an aryl group; Y is a hydrogen atom, or a group capable of being split-off upon a coupling reaction; wherein, when RA is -L-R1, L is a divalent linking group, and R1 is a substituent; and -L-R1 does not represent an alkyl, alkenyl, alkynyl, or aryl group, and -L-R1 does not represent a heterocyclic group that bonds, with a carbon atom therein, to the nitrogen atom of the nitrogen-containing 6-membered ring formed by Q and the -N-CN- moiety.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1326NO – PubChem