Simple exploration of Methyl (R)-N-Boc-2,2-dimethyloxazolidine-4-carboxylate

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IOOC route to substituted chiral pyrrolidines. Potential glycosidase inhibitors

Branched-chain five-membered ring aza-sugar analogues, synthesized from amino acids by an intramolecular oxime-olefin cycloaddition reaction, the IOOC route, were found to be selective glycosidase inhibitors. The derivative 2,4(S)-di(hydroxymethyl)-3(S)-aminopyrrolidine, obtained from D-serine, was about 1 order of potency more active than its enantiomer obtained from L- serine.

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Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2511NO – PubChem