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A one-pot approach using a subsequent Cu(II)/Cu(I) catalysis and a highly diastereodivergent three-component reaction allow an easy access to various aryl-pyrrolo-tetrahydrocarbazoles with the control of up to four variable fragments and two different diastereoselectivities.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H939NO – PubChem

 

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Condensation of malononitrile, ethylcyanacetate and isopropylidene malonate with various O-ethyl cyclic carbamates leads to alpha-(tetrahydroxazole-1,3-ylidene-2) and alpha-(tetrahydroxazine-1,3-ylidene-2) malononitriles, ethylcyanacetates and isopropylidene malonates.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H631NO – PubChem

 

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The preparation method comprises the following steps. recrystallizing the crude carbamastatin crude product through an organic solvent, wherein the organic solvent is mixed solvent, of an alcohol solvent and water; the alcohol solvent is preferably selected from methanol, ethanol or isopropanol, and a high-purity carbamazine,can be prepared by the method. (by machine translation)

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Oxazolidine – Wikipedia,
Oxazolidine | C3H267NO – PubChem

 

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This study is mainly focused on the design of stable, active and selective catalyst for direct synthesis of 2-imidazolidinone (cyclic urea) from ethylenediamine and CO2. Based on the rationale for the catalyst properties needed for this reaction, KF, ZnO and Al2O3 combination was selected to design the catalyst. ZnO/KF/Al2O3 catalyst was prepared by stepwise wet-impregnation followed by the removal of physisorbed KF from the surface. High product yield could be achieved by tuning acid-base sites by varying the composition and calcination temperature. The catalysts were characterized by various techniques like XRD, N2-sorption, NH3-TPD, CO2-TPD, TEM, XPS and FT-IR measurements. It is shown that acidic and basic properties of the solvent can influence the activity and product selectivity for this reaction. Under optimized condition; 180 C, 10 bar and 10 wt.% catalyst in batch mode, 96.3 % conversion and 89.6 % selectivity towards the 2-imidazolidinone were achieved.

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Oxazolidine – Wikipedia,
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The invention relates to a method of creating a carbon-carbon or carbon-heteroatom linkage by reacting an unsaturated compound bearing a leaving group and a nucleophilic compound. More specifically, the invention relates to the creation of a carbon-nitrogen linkage involving the arylation of nitrogenous organic derivatives. The inventive method consists in creating a carbon-carbon or carbon-heteroatom linkage by reacting an unsaturated compound bearing a leaving group and a nucleophilic compound providing a carbon atom or a heteroatom (HE) capable of being substituted for the leaving group, thereby creating a C?C or C-HE linkage. The invention is characterised in that the reaction is carried out in the presence of an effective quantity of a catalyst based on copper and at least one ligand comprising at least one imine function and at least one additional nitrogen atom as chelating atoms

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Oxazolidine – Wikipedia,
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This document discloses molecules having the following formula (?Formula One?): and processes related thereto.

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Oxazolidine – Wikipedia,
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Nucleophilicty of 32 nitrogen nucleophiles belonging to the families of amine, amide, carbamate, amidine, and pyridine have been calculated at the DFT/B3LYP/6-31G (d, p) level of theory using the gas-phase ionization potential based nucleophilicity index N. The calculated gas phase nucleophilicities of the pyridine series correlate well with Mayr’s nucleophilicity values calculated on the basis of experimental quantities and the inverse of electrophilicity index. Local nucleophilicity trend and site selectivity have been analyzed using local nucleophilicity index Nk and the philicity index omegak- In most cases both the two local indices reproduced the experimentally observed trend.

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Oxazolidine – Wikipedia,
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The development of Rh(III)-catalyzed C-H conjugate addition/cyclization reactions that provide access to synthetically useful fused bi- and tricyclic nitrogen heterocycles is reported. A broad scope of C-H functionalization substrates and electrophilic olefin coupling partners is effective, and depending on the nature of the directing group, cyclic imide, amide, or heteroaromatic products are obtained. An efficient synthesis of a pyrrolophenanthridine alkaloid natural product, oxoassoanine, highlights the utility of this method.

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Oxazolidine – Wikipedia,
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A four-step route to the tetracyclic ring system found in a number of indole alkaloids is described using stereoselective dipolar cycloaddition reactions of azomethine ylides. The ylides were derived from N-protected 2-butenylindole-3-carbaldehydes, which were prepared in three steps from 2-methylindole. Condensation of these aldehydes with a variety of alkylamino esters or amino acids or with N-methylhydroxylamine gave the required azomethine ylides or nitrone that undergo intramolecular cycloaddition onto the pendant, unactivated alkene. The cycloaddition sets up two new rings and up to three new stereocentres stereoselectively. After cycloaddition with N-allylglycine, N-deallylation provided the N-unsubstituted product and this constitutes a formal synthesis of the alkaloid deethylibophyllidine. The cycloaddition chemistry was also shown to be amenable as a route to the alkaloid ibophyllidine or epiibophyllidine, although the use of 2-(allylamino)butyric acid to prepare the azomethine ylide can favour competing iminium ion isomerisation and hydrolysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H448NO – PubChem

 

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N-Acyl-2-phenyliminooxazolidines 7 were easily prepared and treated with several amines at room temperature, yielding amides 9 in very high yields.Possible mechanisms for this transformation are briefly discussed.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H545NO – PubChem