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A large scale fusion device like ITER requires high performance electric insulation materials against gamma ray and neutron irradiation, since fusion neutrons will reach superconducting magnets and activate them. Cyanate ester resin has been studied as a strong candidate for a new insulation material for fusion devices, and it has been clarified that the blended resin with epoxy has a potential to survive a design period in the radiation environment. This paper describes the results of molecular structure analysis of the blended resin, heat flux measurements by differential scanning calorimetry and the gamma ray and the fission neutron irradiation effects on interlaminar shear strength (ILSS) at 77 K. The gamma ray irradiation of 10 MGy did not change the ILSS significantly, but the neutron fluence of 1.0 × 1022 n/m 2 (>0.1 MeV) with over 400 MGy degraded the ILSS. It suggests that cyanurate (triagine ring) will have a resistance against irradiation but oxazolidinon will lose the resistance after heavy irradiation.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H862NO – PubChem

 

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This chapter is an update to the earlier Science of Synthesis contribution on the preparation of acyclic and cyclic carbamates, thiocarbamates, selenocarbamates, tellurocarbamates, and phosphinecarboxylates, as well on their applications in organic synthesis. It focuses on the literature published in the period 2013-2017.

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Oxazolidine – Wikipedia,
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SO3H-Functionalized ionic liquids were found to be efficient and reusable catalysts in the hydroamination of sulfonamides, carboxamides, p-nitroaniline and carbamates with nonactivated alkenes. The hydroamination could be performed on a large scale and the acidic ionic liquid catalyst could be reused successfully. Georg Thieme Verlag Stuttgart.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1167NO – PubChem

 

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In the presence of a chiral Lewis acid as co-catalyst, the acid- catalysed 1,3-dipolar cycloaddition reaction yielding trans-3,4-disubstituted pyrrolidines from an azomethine ylide and achiral alpha,beta-unsaturated dipolarophiles proceeded with low enantioselectivity. Therefore a number of alpha,beta-unsaturated dipolarophiles linked to chiral auxiliaries were examined as substrates. Camphorsultam was the best auxiliary and gave good diastereoselectivity (dr=74:26). When combining chiral Lewis acids with a dipolarophile linked to a chiral auxiliary, the enantio-selectivity could be slightly increased. As judged by 13C NMR, the small effect of the chiral Lewis acids on selectivity was probably due to breakdown of the initially formed complex with the dipolarophile caused by the dipole precursor.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H682NO – PubChem

 

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Reference of 1192-07-0, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 1192-07-0, Isoxazolidin-3-one, introducing its new discovery.

According to Deslongchamps’ theory of stereoelectronic control, preferentioal cleavage of a tetrahedral intermediate occurs when there are two lone pairs antiperiplanar to the leaving group.For reasons presented (Perrin and Arrhenius, J.Am.Chem.Soc. 1982, 104, 2839), product studies of hydrolysis of cyclic amidines can test this theory, and initial results supported it.However, those results are ambiguous, owing to a mismatch of leaving abilities.We now find that hydrolysis of three six-membered ring amidines bearing matched leaving groups produces predominantly aminoamide, the product of ring cleavage, and only 3-9percent lactam, as expected from the theory.In contrast, hydrolysis of three five- or seven-membered ring amidines produces substantial (ca. 50percent) lactam.Despite attempts to accomodate these results to the theory, it is concluded that there is no general requirement for two lone pairs antiperiplanar to the leaving group and that stereoelectronic control, even in six-membered ring amidines, contributes less than 2 kcal/mol.

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Oxazolidine – Wikipedia,
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The oxidative degradation of aqueous, concentrated 2-amino-2-methyl-1- propanol (AMP)/monoethanolamine (MEA) mixture has been investigated in batch reactors at temperatures in the range of 100-140C, and oxygen pressures in the range of 250-350 kPa. The oxidation pathway of individual AMP was proposed before attempting to investigate the oxidation of AMP/MEA blend. As compared with degradation of single MEA and AMP, no cross product was found in the degraded AMP/MEA blend under the experimental conditions. This result showed that AMP and MEA could be oxidized in parallel in the mixture. Both the overall degradation rates of MEA and AMP increased with raising temperature and oxygen partial pressure. MEA degraded faster than AMP in the blend under all the experimental conditions. The degradation rate of AMP decreased indicating MEA protects AMP from oxidation in the mixture when initial MEA concentration was increased.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H1119NO – PubChem

 

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Several heterogeneous basic metal oxide catalysts were screened for the synthesis of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different beta-aminoalcohols or 1,2-diamines. Among the several catalysts screened, MgO was found to be the best catalyst, as it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalysts at 80 C within 6 h in ethanol. Basic properties of the metal oxide catalysts were compared using temperature programmed desorption (TPD) studies with CO2. The relationship between the catalyst performance and the basic property of each catalyst has been discussed.

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The first example of simple Re2O7-catalyzed direct dehydrative coupling between allylic alcohols with electron-deficient amines has been achieved under mild and open flask conditions. The protocol has also been successfully applied to benzylic and propargylic alcohols. The mechanistic proof for the SN1-type process has also been provided.

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Oxazolidine – Wikipedia,
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3-Isoxazolidone has been isolated from jack bean seedlings.

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New stannyl enamines derived from N-ethynyl oxazolidin-2-ones have been obtained. We describe for the first time the preparation of N-ethynyl oxazolidin-2-ones using trimethylsilylethynyl iodonium triflate. The first results of transmetallation and quenching experiments with prochiral carbonyl derivatives to give beta-amino alcohols are also described.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H858NO – PubChem