Tran, Hai N.’s team published research in Organic Letters in 24 | CAS: 2185014-88-2

Organic Letters published new progress about 2185014-88-2. 2185014-88-2 belongs to oxazolidine, auxiliary class BOX Ligands, name is (4S,4’S)-2,2′-(Cyclohexane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole), and the molecular formula is C2H4Cl2O3S, Computed Properties of 2185014-88-2.

Tran, Hai N. published the artcileNickel-Catalyzed Enantioselective Hydroboration of Vinylarenes, Computed Properties of 2185014-88-2, the publication is Organic Letters (2022), 24(1), 395-399, database is CAplus and MEDLINE.

The enantioselective hydroboration of vinylarenes catalyzed by a chiral, nonracemic Ni catalyst is presented as a facile method for generating chiral benzylic boronate esters. Various vinylarenes react with bis(pinacolato)diboron (B2pin2) in the presence of MeOH as a hydride source to form chiral boronate esters in up to 92% yield with up to 94% ee. The use of anhydrous Me4NF to activate B2pin2 is crucial for ensuring fast transmetalation to achieve high enantioselectivities.

Organic Letters published new progress about 2185014-88-2. 2185014-88-2 belongs to oxazolidine, auxiliary class BOX Ligands, name is (4S,4’S)-2,2′-(Cyclohexane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole), and the molecular formula is C2H4Cl2O3S, Computed Properties of 2185014-88-2.

Referemce:
https://en.wikipedia.org/wiki/Oxazolidine,
Oxazolidine | C3H7NO – PubChem